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electrochemical fluorination
Electrochemical fluorination (ECF), or electrofluorination, is a foundational organofluorine chemistry method for the preparation of fluorocarbon-based organofluorine compounds.〔G. Siegemund, W. Schwertfeger, A. Feiring, B. Smart, F. Behr, H. Vogel, B. McKusick "Fluorine Compounds, Organic" in "Ullmann’s Encyclopedia of Industrial Chemistry" 2005, Wiley-VCH, Weinheim. 〕 The general approach represents an application of electrosynthesis. The fluorinated chemical compounds produced by ECF are useful because of their distinctive solvation properties and the relative inertness of carbon–fluorine bonds. Two ECF synthesis routes are commercialized and commonly applied, the Simons Process and the Phillips Petroleum Process. Additionally, it is also possible to electrofluorinate in various organic media.〔Fred G. Drakesmith "Electrofluorination of Organic Compounds" Topics in Current Chemistry,Vol. 193, Springer, Berlin-Heidelberg, 1997.〕 Prior to the development of these methods, fluorination with fluorine, a dangerous oxidant, was a dangerous and wasteful process. Also, ECF can be cost effective but it may also result in low yields.
==Simons Process==
The Simons Process entails electrolysis of a solution of an organic compound in a solution of hydrogen fluoride. An individual reaction can be described as:
:R3C–H + HF → R3C–F + H2
In the course of a typical synthesis, this reaction occurs once for each C–H bond in the precursor. The cell potential is maintained near 5–6 V. The anode is nickel-plated. Simons discovered the process in the 1930s at Pennsylvania State College (U.S.), under the sponsorship of the 3M Corporation. The results were not published until after WWII because the work was classified due to its relevance to the manufacture of uranium hexafluoride. In 1949 Simons and his coworkers published a long paper in the Journal of the Electrochemical Society. The Simons process is used for the production of perfluorinated amines, ethers, carboxylic acids, and sulfonic acids. For carboxylic and sulfonic acids, the products are the corresponding acyl and sulfonyl fluorides. The method has been adapted to laboratory-scale preparations. Two noteworthy considerations are (i) the hazards associated with hydrogen fluoride (the solvent and fluorine source) and (ii) the requirement for anhydrous conditions.
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